IGNOU BCHCT-131 Solved Assignment 2024 | B.Sc. CBCS Chemistry
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IGNOU BCHCT-131 Assignment Question Paper 2024
bchct-131-solved-assignment-2024-35c75513-663a-4bae-bede-47f427737c46
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Using a suitable diagram explain the spectral transitions between different energy levels of hydrogen atom. Also name these series of lines and give the region of electromagnetic radiation in which they appear.
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What was the purpose of Davisson and Germer experiment? Explains and analyse its results.
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(a) What is a well-behaved wave function? Illustrate using suitable diagram.
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What are different quantum numbers? Explain their significance.
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Briefly explain the following:
(i) The aufbau principle
(ii) Hund’s rule
(iii) Pauli exclusion principle -
a) Arrange the following compounds in order of decreasing lattice energy:
LiF,MgO,KBr \mathrm{LiF}, \mathrm{MgO}, \mathrm{KBr} . Justify your answer.
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Why does the bond length decrease in the case of multiple bond formation? Explain with the help of an example. Also explain why a multiple bond is stronger than a single bond.
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a) The observed dipole moment of
HI \mathrm{HI} is0.38D 0.38 \mathrm{D} . Calculate the percentage ionic character of the bondingHI \mathrm{HI} if bond distance is161pm 161 \mathrm{pm}
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Draw the resonance structures of carbon monoxide. Also give the electronic configuration of the combining atoms
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Draw the energy level diagram for carbon monoxide molecule. Write its molecular orbitals configuration and calculate its bond order. Comment on its magnetic behaviour.
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Draw all the stereoisomers of 2-bromo-3-chlorobutane and classify them as enantiomers and diastereoisomers.
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(a) What are resolving agents? Give examples of three acidic and three basic resolving agents.
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Draw and explain the energy propile for ring flipping of chair conformation of cyclohexane.
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Arrange the following carbocations in the increasing order of stability and explain the reason for your answer:
A primary carbocation, a tertiary carbocation, a secondary carbocation. -
Arrange the following nucleophiles in the increasing order of their strength and give reason for your answer.
- (a) Define octane number. How does the octane number of a hydrocarbon vary with the following?
(i) Branching of the hydrocarbon chain
(ii) Decrease in the chain length
(iii) Unsaturation
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How would you prepare an alkene using Wittig reaction? Explain the mechanism also.
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What is Markownikoff’s rule? Explain using this rule why 2-bromopropane is the major product of bromination of propene.
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Discuss different methods of preparation of propyne.
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Explain whether the following compounds are aromatic or not?
BCHCT-131 Sample Solution 2024
bchct-131-solved-assignment-2024-ss-10cd7422-4b11-4531-9171-a6445826d855
- Using a suitable diagram explain the spectral transitions between different energy levels of hydrogen atom. Also name these series of lines and give the region of electromagnetic radiation in which they appear.
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Lyman Series: Transitions from higher energy levels
n >= 2 n \geq 2 to then=1 n = 1 level. These lines are in the ultraviolet region of the electromagnetic spectrum. -
Balmer Series: Transitions from higher energy levels
n >= 3 n \geq 3 to then=2 n = 2 level. These lines are in the visible region of the spectrum. -
Paschen Series: Transitions from higher energy levels
n >= 4 n \geq 4 to then=3 n = 3 level. These lines are in the infrared region. -
Brackett Series: Transitions from higher energy levels
n >= 5 n \geq 5 to then=4 n = 4 level, also in the infrared region. -
Pfund Series: Transitions from higher energy levels
n >= 6 n \geq 6 to then=5 n = 5 level, again in the infrared region.
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Lyman Series: This series represents transitions from higher energy levels to the
n=1 n = 1 level. These transitions result in the emission of ultraviolet radiation. -
Balmer Series: These transitions occur from higher levels to the
n=2 n = 2 level, and the emitted radiation falls in the visible spectrum. -
Paschen Series: Transitions to the
n=3 n = 3 level are in the Paschen series, and the radiation emitted is in the infrared region. -
Brackett Series: These are transitions to the
n=4 n = 4 level, with emitted radiation also in the infrared region. -
Pfund Series: This series includes transitions to the
n=5 n = 5 level, with emissions in the infrared region.
- What was the purpose of Davisson and Germer experiment? Explains and analyse its results.
Original Purpose:
Accidental Discovery and Quantum Mechanics:
Experiment Details:
Results and Analysis:
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Wave-Like Behavior: Instead of a random scattering pattern, Davisson and Germer observed a series of concentrated spots. These spots formed a pattern that resembled the diffraction patterns produced by waves, not particles. When the wavelength of these electron waves was calculated, it matched the theoretical prediction made by de Broglie for the wavelength of an electron.
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Confirmation of de Broglie’s Hypothesis: This experiment provided the first solid evidence of de Broglie’s hypothesis of matter waves, suggesting that matter can exhibit wave-like properties, a fundamental concept in quantum mechanics.
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Impact on Physics: The Davisson-Germer experiment’s findings were groundbreaking. They played a significant role in the acceptance of wave-particle duality theory and the broader development of quantum mechanics. This theory fundamentally altered our understanding of how particles at the atomic and subatomic level behave.
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Brillouin Zones Analysis: Later analyses related the experiment’s results to the concept of Brillouin zones in solid state physics, further illustrating the wave nature of electrons and their interactions in crystalline structures.
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